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- W1589067675 abstract "The reactivity of unsaturated compounds Me2EC(SiR3)3 (E = Si, Ge, Sn; SiR3 = SiMe3, SiMePh2) with a variety of organic dienes is studied. The relative yields of products found for [4+2], [2+2], and ene reactions are explained by the electronegativity of E (Si ≈ Sn < Ge), the radius of E (Si ≈ Ge < Sn) and the energy of the E–C bond formed (Si-C > Ge-C > Sn-C). As a result, we found that the trend towards ene reaction and [2+2] cycloaddition decreases and the trend towards [4+2] cycloaddition increases in the direction sila-, germa-, stannaethene." @default.
- W1589067675 created "2016-06-24" @default.
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- W1589067675 date "1997-12-11" @default.
- W1589067675 modified "2023-10-18" @default.
- W1589067675 title "Dieno‐ and Enophilicity of Sila‐, Genua‐, and Stannaethenes" @default.
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- W1589067675 doi "https://doi.org/10.1002/9783527619900.ch20" @default.
- W1589067675 hasPublicationYear "1997" @default.
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