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- W1589592912 abstract "Individual rovibronic transitions are isolated at high resolution from a crowded absorption feature with a fluorescence excitation technique which is based on detection of fluorescence from one and only one rovibronic level. The method is illustrated by resolving four rovibronic transitions from the single rotational line-like feature in the 0, 0 band of the 1Au ← 1Ag (S1 ← S0) absorption of glyoxal vapor. The rotational structure of the 510 fluorescence band is studied as a function of tuning a narrow-band laser line (linewidth < 10−4 cm−1) to various positions in and near this absorption feature. The fluorescence structure proves an extremely sensitive tool for detecting small absorptions, with emission from 12 rovibronic levels being identified. One of the spectra so obtained is a close approximation of true single rotational level fluorescence." @default.
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- W1589592912 date "1978-03-01" @default.
- W1589592912 modified "2023-09-23" @default.
- W1589592912 title "S1-S0 fluorescence after narrow band excitation of glyoxal" @default.
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- W1589592912 doi "https://doi.org/10.1016/0022-2852(78)90229-1" @default.
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