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- W1589805492 abstract "Incorporation of fluorine atoms into organic molecules significantly enhances many of their properties, such as solubility, metabolic stability, and bioavailability. Among organofluorine molecules, trifluoromethylated compounds play a unique and important role in agricultural and medicinal chemistry. An efficient strategy for the synthesis of a variety of trifluoromethylated polyhydroxypyrrolidines is described. This strategy involves a diastereoselective nucleophilic addition reaciton of trimethyl(trifluoromethyl)silane to sugar-derived cyclic nitrones followed by reductive N–O bond cleavage and removal of benzyl groups." @default.
- W1589805492 created "2016-06-24" @default.
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- W1589805492 date "2013-03-08" @default.
- W1589805492 modified "2023-10-07" @default.
- W1589805492 title "Stereoselective Synthesis of Trifluoromethyl Analogues of Polyhydroxypyrrolidines" @default.
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- W1589805492 doi "https://doi.org/10.1002/ejoc.201201599" @default.
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