FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1589871305> ?p ?o ?g. }

• W1589871305 endingPage "5801" @default.
• W1589871305 startingPage "5791" @default.
• W1589871305 abstract "Triphenylvinyl bromide (I) and diphenylvinyl iodide (XII) can be made to undergo replacement of the halogen atom by a phenyl group; n-BuLi (2·5 moles) is added to a mixture of the vinyl halide and o-bromofluorobenzene in ether at −78° followed by warming to −35°. The intermediate o-lithium derivative in the reaction of I could be converted to o-methyltetraphenylethylene (VI) by treatment with methyl iodide or to o-bromotetraphenylethylene (V) with ethylene dibromide. The p-chloro derivatives of I (cis- and trans-IX) undergo the same reaction followed by treatment with ethylene dibromide to give 1-(o-bromophenyl)-2,2-diphenylethylene (X), a different stereoisomer predominating in each case. o-Bromotetraphenylethylene (V) was readily converted back to the lithium reagent with n-BuLi in tetrahydrofuran. Carbonation gave the expected carboxylic acid. With dimethyl carbonate, however, there was formed none of the expected carbonyl addition product but instead up to 25% of 9,10-diphenylphenanthrene (VIII). A study was made of the effect of solvent on the relative amounts of lithium-halogen and lithium-hydrogen exchange in the reaction of n-BuLi with 2,2-diphenylvinyl bromide (XI). It has been found that triphenylvinyl bromide with two models of n-BuLi in ether at room temperature for 24 hr followed by treatment with ethylene dibromide gives as the only dibromide detected 2-(o-bromophenyl)-1,2-diphenylvinyl bromide (XVII). Possible significance of this seemingly selective ortho-metalation reaction is discussed." @default.
• W1589871305 created "2016-06-24" @default.
• W1589871305 creator A5050304939 @default.
• W1589871305 creator A5071301179 @default.
• W1589871305 date "1968-01-01" @default.
• W1589871305 modified "2023-09-23" @default.
• W1589871305 title "The stereospecific arylation of olefins" @default.
• W1589871305 cites W1964171398 @default.
• W1589871305 cites W1967771957 @default.
• W1589871305 cites W1968372235 @default.
• W1589871305 cites W1988095741 @default.
• W1589871305 cites W1990992356 @default.
• W1589871305 cites W2005792262 @default.
• W1589871305 cites W2014731437 @default.
• W1589871305 cites W2017489715 @default.
• W1589871305 cites W2018536305 @default.
• W1589871305 cites W2021793754 @default.
• W1589871305 cites W2026206002 @default.
• W1589871305 cites W2030427332 @default.
• W1589871305 cites W2064118308 @default.
• W1589871305 cites W2083007202 @default.
• W1589871305 cites W2085009444 @default.
• W1589871305 cites W2114536756 @default.
• W1589871305 cites W2124379533 @default.
• W1589871305 cites W2170925413 @default.
• W1589871305 cites W2319397552 @default.
• W1589871305 cites W2319554315 @default.
• W1589871305 cites W2320355570 @default.
• W1589871305 cites W2320440204 @default.
• W1589871305 cites W2324599216 @default.
• W1589871305 cites W2327656212 @default.
• W1589871305 cites W2328575479 @default.
• W1589871305 cites W2328815050 @default.
• W1589871305 cites W2330671865 @default.
• W1589871305 cites W2330860668 @default.
• W1589871305 cites W2334168851 @default.
• W1589871305 cites W4229491178 @default.
• W1589871305 cites W4256329613 @default.
• W1589871305 doi "https://doi.org/10.1016/s0040-4020(01)96310-0" @default.
• W1589871305 hasPublicationYear "1968" @default.
• W1589871305 type Work @default.
• W1589871305 sameAs 1589871305 @default.
• W1589871305 citedByCount "14" @default.
• W1589871305 crossrefType "journal-article" @default.
• W1589871305 hasAuthorship W1589871305A5050304939 @default.
• W1589871305 hasAuthorship W1589871305A5071301179 @default.
• W1589871305 hasConcept C107706546 @default.
• W1589871305 hasConcept C121332964 @default.
• W1589871305 hasConcept C134018914 @default.
• W1589871305 hasConcept C155647269 @default.
• W1589871305 hasConcept C161790260 @default.
• W1589871305 hasConcept C171560689 @default.
• W1589871305 hasConcept C178790620 @default.
• W1589871305 hasConcept C185592680 @default.
• W1589871305 hasConcept C187921627 @default.
• W1589871305 hasConcept C2776099347 @default.
• W1589871305 hasConcept C2776300020 @default.
• W1589871305 hasConcept C2776701986 @default.
• W1589871305 hasConcept C2778444112 @default.
• W1589871305 hasConcept C2778541603 @default.
• W1589871305 hasConcept C2778870691 @default.
• W1589871305 hasConcept C2780073701 @default.
• W1589871305 hasConcept C2780263894 @default.
• W1589871305 hasConcept C2780407432 @default.
• W1589871305 hasConcept C2780471494 @default.
• W1589871305 hasConcept C40875361 @default.
• W1589871305 hasConcept C46062151 @default.
• W1589871305 hasConcept C71924100 @default.
• W1589871305 hasConcept C97355855 @default.
• W1589871305 hasConceptScore W1589871305C107706546 @default.
• W1589871305 hasConceptScore W1589871305C121332964 @default.
• W1589871305 hasConceptScore W1589871305C134018914 @default.
• W1589871305 hasConceptScore W1589871305C155647269 @default.
• W1589871305 hasConceptScore W1589871305C161790260 @default.
• W1589871305 hasConceptScore W1589871305C171560689 @default.
• W1589871305 hasConceptScore W1589871305C178790620 @default.
• W1589871305 hasConceptScore W1589871305C185592680 @default.
• W1589871305 hasConceptScore W1589871305C187921627 @default.
• W1589871305 hasConceptScore W1589871305C2776099347 @default.
• W1589871305 hasConceptScore W1589871305C2776300020 @default.
• W1589871305 hasConceptScore W1589871305C2776701986 @default.
• W1589871305 hasConceptScore W1589871305C2778444112 @default.
• W1589871305 hasConceptScore W1589871305C2778541603 @default.
• W1589871305 hasConceptScore W1589871305C2778870691 @default.
• W1589871305 hasConceptScore W1589871305C2780073701 @default.
• W1589871305 hasConceptScore W1589871305C2780263894 @default.
• W1589871305 hasConceptScore W1589871305C2780407432 @default.
• W1589871305 hasConceptScore W1589871305C2780471494 @default.
• W1589871305 hasConceptScore W1589871305C40875361 @default.
• W1589871305 hasConceptScore W1589871305C46062151 @default.
• W1589871305 hasConceptScore W1589871305C71924100 @default.
• W1589871305 hasConceptScore W1589871305C97355855 @default.
• W1589871305 hasIssue "17" @default.
• W1589871305 hasLocation W15898713051 @default.
• W1589871305 hasOpenAccess W1589871305 @default.
• W1589871305 hasPrimaryLocation W15898713051 @default.
• W1589871305 hasRelatedWork W1580893645 @default.
• W1589871305 hasRelatedWork W1589871305 @default.

• next