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- W1590662964 abstract "1 The influence of magnesium and potassium on the equilibrium catalysed by adenylate kinase has been studied. An equation has been derived which describes the effect of these ions on the equilibrium; values for the metal-nucleotide stability constants, and for the “true” equilibrium constant, [AMP2−] · [ATP4−]/([ADP3−])2, have been calculated, which give the best fit of this equation to the experimental data. 2 Using these constants, the concentrations of all significant species in an adenine nucleotide pool equilibrated by adenylate kinase can be calculated, for any specified total concentrations of magnesium, potassium, and adenine nucleotide pool, at any pH and any pyrophosphate bond content of the adenine nucleotide pool. Magnesium emerges as a significant feedback signal from an adenine nucleotide pool considered as an isolated system. 3 The possible significance of this data with respect to the control of metabolic flux in general and of phosphofructokinase in particular is discussed." @default.
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- W1590662964 date "1970-04-01" @default.
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- W1590662964 title "Magnesium, Potassium, and the Adenylate Kinase Equilibrium. Magnesium as a Feedback Signal from the Adenine Nucleotide Pool" @default.
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- W1590662964 doi "https://doi.org/10.1111/j.1432-1033.1970.tb00940.x" @default.
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