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• W1590731784 abstract "The infrared and Raman spectra of both the high- and low-temperature modifications of sodium d4-borohydride NaBD4 are reported. In order to facilitate the assignment of bands due to isotopic splitting in NaBD4, the infrared spectra of solid solutions of the BD4−-ions imbedded in face-centered cubic alkali halide lattices are also reported. By means of the splitting of the degenerate modes v2, v3, and v4 in the infrared and Raman spectra of NaBD4, it is shown that at temperatures below that of the phase transition temperature at 197 ± 1 °K, the crystal symmetry of the compound is transformed from face-centered cubic to body-centered tetragonal. The temperature dependence of the infrared bands in NaBD4 also reveals that a close resemblance exists between the phase transition in this compound and that in NaBH4." @default.
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• W1590731784 date "1971-08-01" @default.
• W1590731784 modified "2023-09-26" @default.
• W1590731784 title "Low-temperature infrared studies" @default.
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• W1590731784 doi "https://doi.org/10.1016/0022-2860(71)85044-5" @default.
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