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- W1591235217 abstract "α-Acyloxy derivatives of straight-chain aliphatic sulfides in boiling t-butyl alcohol give mercaptals. Thus, α-benzoyloxy di-n-propyl sulfive and α-acetoxy di-n-butyl sulfide yielded propio-aldehyde di-n-propyl mercaptal and butyroaldehyde di-n-butyl mercaptal, respectively. However, 2-benzoyloxytetrahydrothiophene gave a dimer of dihydrothiophene. Pyrolysis in absence of alcohol of acyloxy derivatives of sulfides results in unsaturated sulfides. Thus, α-acetoxy and α-benzoyloxy derivatives of diethyl sulfide and tetrahydrothiophene yielded ethyl vinyl sufide and 2,3-dihydrothiophene, respectively." @default.
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- W1591235217 date "1962-01-01" @default.
- W1591235217 modified "2023-10-15" @default.
- W1591235217 title "Reactions of t-butyl peresters—V" @default.
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- W1591235217 doi "https://doi.org/10.1016/s0040-4020(01)92743-7" @default.
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