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- W1591359989 abstract "An expression is obtained for the alternating stripping current from a continuous mercury film electrode for a linear potential perturbation. Since the ac depends on the mean surface concentrations of the reduced and oxidized states, it is necessary to solve the dc problem for a linear potential sweep. This is done in two ways: (i) by assuming that the linear sweep can be considered as a series of potential steps and applying the equations developed by Osteryoung and Christie; (ii) by applying the rigorous solution proposed by Garcia. The mean surface concentrations were calculated as a function of the electrode thickness l and the applied potential E. The ac response is analyzed as a function of l, E, and the frequency Ω. The results indicate that, at very low l, the ac is a linear function of l and Ω. The peak potential shifts in the negative direction as l decreases. For quasi-reversible processes there is a frequency Ωlim for which the ac is controlled only by charge transfer; Ωlim increases as the thickness decreases." @default.
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- W1591359989 date "1994-07-01" @default.
- W1591359989 modified "2023-09-27" @default.
- W1591359989 title "Ac stripping voltammetry from mercury film electrodes" @default.
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- W1591359989 doi "https://doi.org/10.1016/0022-0728(93)e0325-x" @default.
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