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- W1592011444 abstract "The synthesis of novel hyperbranched glyco-conjugated polymers, prepared by the ring-opening multibranching polymerizations of anhydro and dianhydro sugars, is described. The hyperbranched glyco-conjugated polymers were formed by the cationic polymerization of 1,6-anhydro-β-D-hexopyranose, 1,4-anhydrotetritol, 2,3-anhydrotetritol, and 1,2:5,6-dianhydro-D-mannitol. These polymerizations proceeded without gelation to produce water-soluble hyperbranched glyco-conjugated polymers with controlled molecular weights and narrow polydispersities. This chapter also details the preparation and encapsulation-release property of novel amphiphilic hyperbranched polymers with a micellar characteristic as a single molecule, which are referred to as a ‘unimolecular micelle’ or ‘unimolecular nanocapsule’. The amphiphilic hyperbranched polymers consisting of a hydrophilic hyperbranched glyco-conjugated polymer core and hydrophobic shell possessed an encapsulation ability for hydrophilic guest molecules and the controlled release property of the encapsulated guest molecules, e.g. the biodegradable unimolecular reversed micelle consisting of a hyperbranched D-mannan core and a poly(L-lactide) shell, and the pH-sensitive unimolecular reversed micelle consisting of a hyperbranched D-glucan core and L-leucine ethyl ether shell." @default.
- W1592011444 created "2016-06-24" @default.
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- W1592011444 date "2011-04-27" @default.
- W1592011444 modified "2023-10-10" @default.
- W1592011444 title "Hyperbranched Glyco‐Conjugated Polymers" @default.
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- W1592011444 doi "https://doi.org/10.1002/9780470825150.ch7" @default.
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