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- W1592022789 abstract "X-Ray crystal structures of six complexes of the type M3(CO)10(L)2 (M = Ru, L = PPh3, PPh(OMe)2, and P(OCH2CF33; M = Os, L = PPh3, PPh(OMe)2 and P(OMe)3) have been determined. All contain a triangular M3 core; the two phosphorus ligands occupy equatorial positions on adjacent metal atoms so that they are approximately trans to each other at the ends of the M-M vector. In contrast to complexes M3(CO)11(L), there is no prounounced lengthening of the MM bonds cis to the group 15 ligand. Other features, including twisting of the ML4 groups to distort the D3h symmetry towards D3, are similar to those found for monosubstituted complexes. Thermal reactions between Os3(CO)12) and P(OMe)3, which afford Os3(CO)12-n {P(OMe)3}n (n = 1–4), are described. Crystal data: Ru3(CO)10(PPh3)2: orthorhombic, P212121, τa 34.636(15), b 17.007(10)(10), c 14.806(4) Å, U 8721(7) Å3, Z = 8, N0 (number of ‘observed’ data with I > 3σ(I) = 4773, R = 0.071, R′ = 0.080; Os3(CO)10(PPh32: monoclinic, P21/n, a 17.104(6), b 34.507(11), c 14.832(6) Å, β 92.28(3)°, U 8747(5) Å3 Z = 8, N0 = 8011, R = 0.048, R′ = 0.040; Ru3(CO)10{PPh(OMe)2}2: monoclinic, Pc, a 9.014(4), b 8.545(4), c 21.728(5) Å, β 100.77(3)°, U 1644(1) Å3, Z = 2, N0 = 5269, R = 0.024, R′ = 0.027; Os3(CO)10{PPh(OMe)2}2: monoclinic, Pc, a 9.007(5), b 8.565(7), c 21.716(12) Å, β 100.87(5)°, U 1645(1) Å3, Z = 2, N0 = 5266, R = 0.041, R′ = 0.043; Ru3(CO)10{P(OCH2CF3)3}2: orthorhombic, P212121, a 29.79(2), b 15.827(8), c 8.283(4) Å, U 3906(3) Å3, Z = 4, N0 = 2652, R = 0.063, R′ = 0.070; Os3(CO)10{P(OMe)3}2: triclinic, P1, a 24.955(10), b 9.439(4), c 8.944(4), Å, a 84.02(3), β (3), γ 84.18(3)°, U 2083(1) Å3, Z = 3, N0 = 40.84, R = 0.057, R′ = 0.068." @default.
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- W1592022789 date "1988-06-01" @default.
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- W1592022789 title "Cluster chemistry" @default.
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- W1592022789 doi "https://doi.org/10.1016/0022-328x(88)80281-x" @default.
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