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• W1592316617 abstract "The ultra-violet, visible and near infra-red absorption spectra of the following acetyl-acetonato complexes are reported: Ti(acac)3, V(acac)3, Cr(acac)3, Mn(acac)3, Fe(acac)3, and Co(acac)3. In this series of complexes the π → π∗ transition energy increases with increasing number of dξ-electrons and this is attributed to metal-ligand π-interaction. In order to explain the “normal” value of the ligand field splitting parameter Δ, it is proposed that the metal-ligand π-interaction occurs between dξ-orbitals of the metal and both higher, empty, π∗-orbitals and lower, filled, π-orbitals of the ligands. Other factors affecting the π → π∗ transition energy are also discussed. Electron transfer bands, which are observed in the 300–400 mμ region, have been assigned to the dξ → π4. The dξ → dγ transition are discussed briefly. In each complex the assignments are discussed in detail. In the case of the π → π∗ transition in Cr(acac)3 the assignment differs from that made by previous workers." @default.
• W1592316617 created "2016-06-24" @default.
• W1592316617 creator A5070073771 @default.
• W1592316617 date "1961-12-01" @default.
• W1592316617 modified "2023-09-23" @default.
• W1592316617 title "Electronic absorption spectra of acetyl-acetonato complexes—I" @default.
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• W1592316617 doi "https://doi.org/10.1016/0022-1902(61)80297-2" @default.
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