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- W1592931614 abstract "The effect of the ion-exchange capacity of the concentrator column on the success of the preconcentration process is discussed for the case of anion analysis using non-suppressed ion chromatography. Monovalent anions such as chloride and nitrite are shown to be subject to self-elution during the sample loading process and losses of these ions occurs at levels of loaded sample well below the total ion-exchange capacity of the concentrator column. It is therefore the effective ion-exchange capacity which is of importance, rather than the total ion-exchange capacity. The ion-exchange capacity of the concentrator column is determined largely by the ion-exchange capacity of the analytical column used and in this work, optimal results were achieved when the capacity of the concentrator column was approximately 40% of that of the analytical column. The type of resin used in the concentrator column and the geometry of the column housing are also shown to exert significant effects." @default.
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- W1592931614 date "1987-01-01" @default.
- W1592931614 modified "2023-09-26" @default.
- W1592931614 title "Studies on sample preconcentration in ion chromatography" @default.
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- W1592931614 doi "https://doi.org/10.1016/s0021-9673(01)94411-5" @default.
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