FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W159311108> ?p ?o ?g. }

• W159311108 endingPage "262" @default.
• W159311108 startingPage "245" @default.
• W159311108 abstract "Electrochemical fixation of carbon dioxide in organic compounds with C–C bond formation yielding carboxylic acids is focused and reviewed in this chapter. Electrolysis of organic compounds in the presence of carbon dioxide results in efficient fixation of carbon dioxide in organic compounds with C–C bond formation to yield the corresponding carboxylic acids. When electrolysis is carried out in one-compartment electrochemical cell (undivided cell) using magnesium or aluminum as an anode material, efficient carboxylation can be achieved to give carboxylic acids in high yields. Electrochemical carboxylation is sometimes carried out in the presence of transition-metal catalyst, such as nickel, palladium, and their complexes, or electron transfer mediator, the use of which often results in drastic enhancement and control of chemo- and regioselectivity and efficiency of carbon dioxide fixation. Various organic compounds can be electrochemically carboxylated to give useful carboxylic acids. Some of them cannot be synthesized by conventional chemical fixation of carbon dioxide. One notable synthetic application of electrochemical fixation of carbon dioxide is synthesis of 2-arylpropanoic acids, nonsteroidal anti-inflammatory drugs (NSAIDs), and their useful precursors and derivatives. Electrochemical fixation of carbon dioxide also takes place by using supercritical carbon dioxide (scCO2), which can be realized under relatively moderate conditions (Tc = 31 °C, Pc = 7.5 MPa). By using acetonitrile as a cosolvent, efficient electrochemical fixation in scCO2 in organic compounds can be achieved and carboxylic acids including NSAIDs and their precursors can be obtained in high yields. In this chapter, these results are widely introduced with several representative examples." @default.
• W159311108 created "2016-06-24" @default.
• W159311108 creator A5059802624 @default.
• W159311108 date "2014-01-01" @default.
• W159311108 modified "2023-09-25" @default.
• W159311108 title "Electrochemical Fixation of Carbon Dioxide" @default.
• W159311108 cites W175923001 @default.
• W159311108 cites W1968585717 @default.
• W159311108 cites W1975123872 @default.
• W159311108 cites W1978000040 @default.
• W159311108 cites W1978687957 @default.
• W159311108 cites W1980795333 @default.
• W159311108 cites W1980917694 @default.
• W159311108 cites W1982392755 @default.
• W159311108 cites W1984268129 @default.
• W159311108 cites W1984559073 @default.
• W159311108 cites W1985255503 @default.
• W159311108 cites W1985620707 @default.
• W159311108 cites W1985684227 @default.
• W159311108 cites W1987019609 @default.
• W159311108 cites W1987791546 @default.
• W159311108 cites W1992466629 @default.
• W159311108 cites W1999148870 @default.
• W159311108 cites W1999418455 @default.
• W159311108 cites W2005053866 @default.
• W159311108 cites W2005592971 @default.
• W159311108 cites W2009358910 @default.
• W159311108 cites W2013221909 @default.
• W159311108 cites W2013308252 @default.
• W159311108 cites W2015000309 @default.
• W159311108 cites W2018494434 @default.
• W159311108 cites W2020120897 @default.
• W159311108 cites W2021944756 @default.
• W159311108 cites W2023517604 @default.
• W159311108 cites W2024422409 @default.
• W159311108 cites W2026361700 @default.
• W159311108 cites W2029772318 @default.
• W159311108 cites W2032038621 @default.
• W159311108 cites W2032280382 @default.
• W159311108 cites W2033043103 @default.
• W159311108 cites W2033403940 @default.
• W159311108 cites W2034853546 @default.
• W159311108 cites W2037438987 @default.
• W159311108 cites W2040444111 @default.
• W159311108 cites W2040548641 @default.
• W159311108 cites W2042375903 @default.
• W159311108 cites W2046949848 @default.
• W159311108 cites W2052795683 @default.
• W159311108 cites W2057047984 @default.
• W159311108 cites W2058546426 @default.
• W159311108 cites W2059294376 @default.
• W159311108 cites W2061828438 @default.
• W159311108 cites W2064670079 @default.
• W159311108 cites W2065037532 @default.
• W159311108 cites W2066428178 @default.
• W159311108 cites W2066673070 @default.
• W159311108 cites W2067608164 @default.
• W159311108 cites W2071366496 @default.
• W159311108 cites W2077019465 @default.
• W159311108 cites W2080847983 @default.
• W159311108 cites W2084261650 @default.
• W159311108 cites W2084994530 @default.
• W159311108 cites W2085228185 @default.
• W159311108 cites W2085355772 @default.
• W159311108 cites W2097376958 @default.
• W159311108 cites W2098253660 @default.
• W159311108 cites W2108276149 @default.
• W159311108 cites W2118369167 @default.
• W159311108 cites W2119079218 @default.
• W159311108 cites W2119341174 @default.
• W159311108 cites W2171966932 @default.
• W159311108 cites W2335582634 @default.
• W159311108 cites W2409938079 @default.
• W159311108 cites W2527590627 @default.
• W159311108 cites W2949608140 @default.
• W159311108 cites W2950019748 @default.
• W159311108 cites W2950020288 @default.
• W159311108 cites W2950658315 @default.
• W159311108 cites W2951128395 @default.
• W159311108 cites W2951225629 @default.
• W159311108 cites W2951491799 @default.
• W159311108 cites W2952037887 @default.
• W159311108 cites W2952176051 @default.
• W159311108 cites W2952276760 @default.
• W159311108 cites W2952299149 @default.
• W159311108 cites W2952575596 @default.
• W159311108 cites W2972320547 @default.
• W159311108 cites W310993244 @default.
• W159311108 cites W4244020548 @default.
• W159311108 cites W4241751484 @default.
• W159311108 doi "https://doi.org/10.1007/978-3-642-44988-8_10" @default.
• W159311108 hasPublicationYear "2014" @default.
• W159311108 type Work @default.
• W159311108 sameAs 159311108 @default.
• W159311108 citedByCount "3" @default.
• W159311108 countsByYear W1593111082019 @default.
• W159311108 countsByYear W1593111082023 @default.
• W159311108 crossrefType "book-chapter" @default.

• next