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- W1593290218 abstract "The intermediate products of the reaction between copper(II) dithiocarbamate complex and some Lewis acids (HgI2, HgBr2, GeCl4, AsBr3, CoCl2, C(NO2)4) as well as some organometallic compounds (SnEt4 and PbEt4) were studied using EPR spectroscopy. In non-polar and non-coordinating solvents HgI2, HgBr2 and GeCl4 formed adducts with Cu(dtc)2, whereas in polar and coordinating solvents the mixed-ligand complexes of the type Cu(dtc)+…A−(A = HgX3) were obtained with a complex counterion in the second coordination sphere of copper(II). With C(NO2)4 the intermediate reaction product in non-polar solvents was assumed to be Cu(dtc)·NO2 which dissociates to Cu(dtc)+…NO2− in polar solvents. Similar EPR spectra were obtained with SnEt4 and PbEt4. The reaction of Cu(dtc)2 with CoCl2, AsBr3 and SbCl3 yielded the mixed-ligand complexes of the type Cu(dtc)Xn (n = 1 or 2) exhibiting well resolved superhyperfine splitting from one or two halogen nuclei. The influence of the medium on the above interaction is also discussed." @default.
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- W1593290218 date "1984-01-01" @default.
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- W1593290218 title "Studies on the intermolecular interactions of metal chelate complexesIX" @default.
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- W1593290218 doi "https://doi.org/10.1016/s0277-5387(00)88111-5" @default.
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