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• W159333780 abstract "The infrared spectra (33 to 400 cm−1) of gaseous, liquid, and polycrystalline chloro- and bromocyclopentane have been investigated. Raman spectra of the liquid and solid samples were recorded for the same frequency region and depolarization ratios were measured for the liquids. The C-X and ring-puckering vibrations have been assigned on the basis of a molecule with Cs symmetry. Although the barrier to pseudorotation has been found to be relatively small (<4 kcalmole) for each molecule, the energy difference between the forms with the halogen atom in the axial or equatorial orientations is sufficiently large for the a′ C-X bending and a″ ring-puckering modes to appear as doublets in the ambient temperature spectra. From a temperature study of the Raman spectra on “neat” chloro- and bromocyclopentane, enthalpy differences of 344 and 612 cal/ mole were calculated, respectively." @default.
• W159333780 created "2016-06-24" @default.
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• W159333780 date "1971-07-01" @default.
• W159333780 modified "2023-09-23" @default.
• W159333780 title "Vibrational spectra and structure of small ring compounds" @default.
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• W159333780 doi "https://doi.org/10.1016/0022-2860(71)85014-7" @default.
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