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- W1593973237 abstract "Reaction of [(PPh3)2Pt(C2H4)] with 5,6-dimethyl-2,1,3-benzothiadiazole affords [Pt2S{N(6−μ−N︹−4,5−Me2C6H2)}(μ−PPh2)(PPh3)2Ph]. A crystal structure determination shows that one of the Pt-atoms is inserted into one of the NS bonds. The two Pt-atoms are bridged by the amino groups produced by this insertion, and by a diphenylphosphido group which is formed by insertion of the other Pt-atom into a PC bond. The bond distances in the six-membered heterocyclic PtSNCC−μ−N︹ ring indicate an extensive electron delocalization. The31P-NMR spectrum reveals a large upfield shift for the bridging diphenylphosphido group, which is consistent with its presence in a four-membered ring." @default.
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- W1593973237 date "1978-07-01" @default.
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- W1593973237 title "Cumulated double bond systems as ligands" @default.
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- W1593973237 doi "https://doi.org/10.1016/s0022-328x(00)90428-5" @default.
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