Matches in SemOpenAlex for { <https://semopenalex.org/work/W1594010829> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W1594010829 endingPage "55" @default.
- W1594010829 startingPage "35" @default.
- W1594010829 abstract "The possibility of a new overtone band in the infrared absorption spectrum of tetrahedral XY4 molecules is investigated theoretically. This band is associated with the E vibrational part of the first overtone of an infrared active fundamental. The new band is active only through vibration-rotation interactions. Its intensity is very small compared to that of the F2 vibrational part of the same overtone. Formulas for relative intensities and matrix elements of the Hamiltonian are calculated. The selection rules imply a single P, Q, and R branch. The tetrahedral splittings of the vibration-rotation levels are determined by only two parameters: Dt and γ′3t ≡ 13 (Z3s + 6Z3t). A possible favorable case for the observation of the band may be CD4 at about 4700 cm−1. With the assumption that γ′3t ⪢ Dt, the tetrahedral splittings and relative intensities are calculated numerically through J = 7 for this case." @default.
- W1594010829 created "2016-06-24" @default.
- W1594010829 creator A5044709791 @default.
- W1594010829 date "1965-05-01" @default.
- W1594010829 modified "2023-09-27" @default.
- W1594010829 title "Theory of vibration-rotation interactions in spherical top molecules" @default.
- W1594010829 cites W1530628942 @default.
- W1594010829 cites W1572103397 @default.
- W1594010829 cites W1965804557 @default.
- W1594010829 cites W1966419803 @default.
- W1594010829 cites W1997131853 @default.
- W1594010829 cites W2070980396 @default.
- W1594010829 cites W2323627149 @default.
- W1594010829 cites W3082642350 @default.
- W1594010829 doi "https://doi.org/10.1016/0022-2852(65)90083-4" @default.
- W1594010829 hasPublicationYear "1965" @default.
- W1594010829 type Work @default.
- W1594010829 sameAs 1594010829 @default.
- W1594010829 citedByCount "11" @default.
- W1594010829 countsByYear W15940108292013 @default.
- W1594010829 countsByYear W15940108292020 @default.
- W1594010829 crossrefType "journal-article" @default.
- W1594010829 hasAuthorship W1594010829A5044709791 @default.
- W1594010829 hasConcept C105239961 @default.
- W1594010829 hasConcept C120665830 @default.
- W1594010829 hasConcept C121332964 @default.
- W1594010829 hasConcept C124806180 @default.
- W1594010829 hasConcept C126255220 @default.
- W1594010829 hasConcept C127709339 @default.
- W1594010829 hasConcept C130787639 @default.
- W1594010829 hasConcept C158355884 @default.
- W1594010829 hasConcept C184779094 @default.
- W1594010829 hasConcept C185592680 @default.
- W1594010829 hasConcept C198394728 @default.
- W1594010829 hasConcept C2524010 @default.
- W1594010829 hasConcept C32909587 @default.
- W1594010829 hasConcept C33923547 @default.
- W1594010829 hasConcept C38615331 @default.
- W1594010829 hasConcept C41999313 @default.
- W1594010829 hasConcept C4839761 @default.
- W1594010829 hasConcept C62520636 @default.
- W1594010829 hasConcept C74050887 @default.
- W1594010829 hasConcept C8010536 @default.
- W1594010829 hasConceptScore W1594010829C105239961 @default.
- W1594010829 hasConceptScore W1594010829C120665830 @default.
- W1594010829 hasConceptScore W1594010829C121332964 @default.
- W1594010829 hasConceptScore W1594010829C124806180 @default.
- W1594010829 hasConceptScore W1594010829C126255220 @default.
- W1594010829 hasConceptScore W1594010829C127709339 @default.
- W1594010829 hasConceptScore W1594010829C130787639 @default.
- W1594010829 hasConceptScore W1594010829C158355884 @default.
- W1594010829 hasConceptScore W1594010829C184779094 @default.
- W1594010829 hasConceptScore W1594010829C185592680 @default.
- W1594010829 hasConceptScore W1594010829C198394728 @default.
- W1594010829 hasConceptScore W1594010829C2524010 @default.
- W1594010829 hasConceptScore W1594010829C32909587 @default.
- W1594010829 hasConceptScore W1594010829C33923547 @default.
- W1594010829 hasConceptScore W1594010829C38615331 @default.
- W1594010829 hasConceptScore W1594010829C41999313 @default.
- W1594010829 hasConceptScore W1594010829C4839761 @default.
- W1594010829 hasConceptScore W1594010829C62520636 @default.
- W1594010829 hasConceptScore W1594010829C74050887 @default.
- W1594010829 hasConceptScore W1594010829C8010536 @default.
- W1594010829 hasIssue "1" @default.
- W1594010829 hasLocation W15940108291 @default.
- W1594010829 hasOpenAccess W1594010829 @default.
- W1594010829 hasPrimaryLocation W15940108291 @default.
- W1594010829 hasRelatedWork W1594010829 @default.
- W1594010829 hasRelatedWork W1966670030 @default.
- W1594010829 hasRelatedWork W1971949921 @default.
- W1594010829 hasRelatedWork W1974772161 @default.
- W1594010829 hasRelatedWork W1994189475 @default.
- W1594010829 hasRelatedWork W2037960030 @default.
- W1594010829 hasRelatedWork W2059936557 @default.
- W1594010829 hasRelatedWork W2067474125 @default.
- W1594010829 hasRelatedWork W2077338837 @default.
- W1594010829 hasRelatedWork W2081370796 @default.
- W1594010829 hasVolume "16" @default.
- W1594010829 isParatext "false" @default.
- W1594010829 isRetracted "false" @default.
- W1594010829 magId "1594010829" @default.
- W1594010829 workType "article" @default.