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- W1594176044 abstract "The CeO2-ZrO2-γ-Al2O3 nanocomposite was synthesized through the sol-gel route by mixing a boehmite sol (AlOOH) with an appropriate amount of metal nitrates. By using this multicomponent sol, crack and pinhole free mesoporous membranes were successfully fabricated on an asymmetric porous α-Al2O3 support through dip coating process. The hydrothermal (up to 75% steam) stability of the mesoporous membranes was studied in terms of hydrogen gas permeance at 500EC, phase structure, surface microstructure and pore size distribution. The pore size distribution measurements were conducted directly on the membranes by a nano-permporometer. Among the tested samples with different molar compositions of CeO2-ZrO2-γ-Al2O3, only the mesoporous CeO2-ZrO2-γ-Al2O3 membrane with a molar ratio of 10:10:80 mol% was found to be the most effective membrane under the hydrothermal condition at 500EC. The ternary CeO2-ZrO2-γ-Al2O3 system retained its structure (order and porosity) after crystallization on an α-Al2O3 porous support and subsequent hydrothermal treatment for over 50 h. The hydrothermal test indicates that the mesoporous membrane developed in this study is viable to be used as an intermediate layer for fabricating a multilayer hydrogen separation membrane reactor for the methane steam reforming reaction." @default.
- W1594176044 created "2016-06-24" @default.
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- W1594176044 date "2009-02-01" @default.
- W1594176044 modified "2023-10-17" @default.
- W1594176044 title "Mesoporous CeO2-ZrO2-γ-Al2O3nanocomposite membranes exhibiting remarkable hydrothermal stability" @default.
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- W1594176044 doi "https://doi.org/10.5004/dwt.2009.304" @default.
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