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- W1594196608 abstract "Abstract Structure, positional, and thermal parameters of ND4I were studied at high pressures up to 90 kbar and low temperatures down to 10 K using time-of-flight neutron diffraction. The phase transition from a disordered CsCI-type cubic phase ND4I(II) into a recently discovered high pressure phase ND4I(V) was observed at P = 80(5) kbar. Surprisingly, the structure of the high pressure phase V was found to bear a strong resemblance to that of the ambient pressure, low-temperature phase III - tetragonal structure with an antiparallel ordering of ammonium ions, space group P4/nmm. The critical value of the deuterium positional parameter corresponding to the II-V transition is close to the one for the phase transition between the disordered and ordered CsCl-type cubic phases II and IV in other ammonium halides." @default.
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- W1594196608 date "2000-08-01" @default.
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- W1594196608 title "Structural study of ND4I at high pressures and low temperatures" @default.
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