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- W1594313377 abstract "Abstract We describe herein the asymmetric total synthesis of sphingofungin E, which has potent immunosuppressive activity. Key steps include asymmetric desymmetrization by bromolactonization, stereocontrolled construction of four contiguous stereogenic centers through allylic C–H oxidation and epoxide ring opening, regioselective elongation of a dialdehyde, and Hofmann rearrangement by using PhI(OCOCF 3 ) 2 ." @default.
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- W1594313377 date "2013-09-19" @default.
- W1594313377 modified "2023-10-10" @default.
- W1594313377 title "Stereocontrolled Total Synthesis of Sphingofungin E" @default.
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- W1594313377 doi "https://doi.org/10.1002/ejoc.201301065" @default.
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