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- W1594536623 abstract "We have successfully incorporated multiple transition metals into the MFI framework. The incorporation of vanadium into the framework improved the catalytic activity for the epoxidation of propylene. We demonstrated that propylene oxide could be prepared in high yield without any major byproducts. This route is environmentally more acceptable than the current production process since hydrogen peroxide is a clean oxidant. We also demonstrated that large pore and mesoporous materials such as Ti-Beta and Ti-MCM-41 are effective catalysts for the epoxidation of bulky molecules. For the epoxidation of bulky mono olefins both Ti-Beta and Ti-MCM-41 were very active and selective. However, for bulky molecules having two olefinic groups, such as 4-vinyl- cyclohexene only one double bond was rapidly epoxidized. With Ti-MCM-41 we demonstrated that selectivity and activity for the epoxidation of cyclohexene significantly improved after silylation or removal of water from the reaction media." @default.
- W1594536623 created "2016-06-24" @default.
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- W1594536623 date "1999-01-01" @default.
- W1594536623 modified "2023-10-14" @default.
- W1594536623 title "New transition metal-containing molecular sieves for selective liquid phase oxidation" @default.
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- W1594536623 doi "https://doi.org/10.1016/s0167-2991(99)80248-1" @default.
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