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- W159459500 abstract "High osmotic pressure chromatography (HOPC) was applied to preparative separation of poly(e-caprolactone), a biodegradable polymer, by molecular weight (MW). When the solvent was toluene, a near-ϑ solvent for the polymer, the MW distribution was narrow in all of the separated fractions except late fractions. In dioxane, which is a good solvent, in contrast, the MW distribution narrowed only in early fractions. The difference is explained by a recent computer simulation study on partitioning in ϑ solvent and a concept of self-adjusting pore size by adsorbed polymer." @default.
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- W159459500 date "2002-07-25" @default.
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- W159459500 title "High Osmotic Pressure Chromatography of Poly(ε-caprolactone) in Near-ϑ Solvent" @default.
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- W159459500 doi "https://doi.org/10.1021/ma020524e" @default.
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