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- W1596042017 abstract "Superacid supported catalytic membranes were found to be active and very selective in the partial oxidation of light paraffins (C 1 -C 2 ) to the corresponding alcohols and aldehydes with H 2 O 2 under mild conditions (T R : 80-110 °C; P R : 1,4 bar) in a three phase catalytic membrane reactor (3PCMR). Among different catalytic membranes investigated, Nafion based ones showed the best performance in terms of both activity and selectivity. Addition of Fe 2+ ions in the liquid phase enhances the reaction rate. A reaction pathway based on the electrophilic hydroxylation of the C-H bond on superacid sites and subsequent reaction of the activated paraffin with OH radicals has been proposed." @default.
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- W1596042017 date "1998-01-01" @default.
- W1596042017 modified "2023-09-23" @default.
- W1596042017 title "Partial Oxidation of Light Paraffins on Supported Superacid Catalytic Membranes" @default.
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- W1596042017 doi "https://doi.org/10.1016/s0167-2991(98)80472-2" @default.
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