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- W1596579265 abstract "Abstract The solid solubility of tin in silicon has been determined in the range from 800°C to the melting point of silicon, using crystal-pulling and thermal-gradient crystallization techniques. The distribution coefficient, k , of tin in silicon falls from 0.016 at the melting point of silicon to about 6.5 × 10 −4 at 800°C. Earlier work on the tin-germanium system has also been extended. The form of the temperature-dependence of k is similar for both systems and does not fit into the correlation recently proposed by Hall ( J. Phys. Chem. Solids 3 , 63 (1957)). For these two systems the observed temperature-dependence of k can be explained as being due in a large measure to departures from ideality in the liquid state. Binding energies of tin in germanium and silicon calculated from the solid-solubility data compare favorably with binding energies calculated using Allen 's reciprocal mean postulate for covalent bond energies (J. Chem. Phys. 27, 810 (1957))." @default.
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- W1596579265 date "1959-01-01" @default.
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- W1596579265 title "On the temperature-dependence of the distribution coefficient" @default.
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- W1596579265 doi "https://doi.org/10.1016/0022-3697(59)90091-5" @default.
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