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- W1596892904 abstract "The kinetics and thermodynamics of the spontaneous condensation between monoalcohols (trans-2-hexene-1-ol, 1-octanol, geraniol) and commercial hydroxytelechelic polybutadiene G1000 with propyl isocyanate and phenyl isocyanate in toluene were examined. In all the condensations studied, the third order law is fulfilled. Deviations from the second order law are observed for conversions higher than 60 to 80%. In all cases, autoassociation of the alcohols plays an important role. The rate constants increase with decreasing concentration of hydroxyls and autocatalysis is noticeable. In comparison with the monoalcohols, the different behaviour of the G1000 diol should be due to its trend to be strongly associated by its two hydroxylated chain ends." @default.
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- W1596892904 date "1983-08-01" @default.
- W1596892904 modified "2023-09-25" @default.
- W1596892904 doi "https://doi.org/10.1002/macp.1983.021840813" @default.
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