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- W1597215906 abstract "Three amine-occluding open-framework cobalt phosphates, CoPO4-n (n=1–3) have been synthesized from aqueous-alcoholic systems of Co(Ac)2-H3PO4-R-EG-H2O, where R stands for an amine and EG for ethylene glycol. It is found that diamines can be exclusively used as the structure-directing templates during the crystallization of open-framework cobalt phosphates. The structures of CoPO4-n were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), inductively coupled plasma (ICP) analysis, infrared spectroscopy (IR) and UV-Vis diffuse reflectance spectroscopy (DRS). The as-synthesized compounds are all blue in color and exhibit UV-Vis spectra characteristic of tetrahedrallycoordinated Co atoms. Thermal analysis shows that the templates occluded in CoPO4-n decompose endothermally at 400–450 °C, and after the template decomposition, the materials become X-ray amorphous." @default.
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- W1597215906 date "1997-01-01" @default.
- W1597215906 modified "2023-09-22" @default.
- W1597215906 title "Synthesis and characterization of novel open-framework cobalt phosphates from aqueous-alcoholic systems" @default.
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- W1597215906 doi "https://doi.org/10.1016/s0167-2991(97)80579-4" @default.
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