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- W1597448329 abstract "/EtOH （1/1 v/v）, for differenttimes. It was found that both the initial modulus and the stress peak on stretching de-creased in magnitude with increasing swelling time and the peak disappeared entirely after1 hour of swelling. On further swelling the initial modulus increased somewhat and a smallstress peak re-appeared after swelling for 2 h. The disappearance of the stress peak afterswelling is interpreted as the result of disruption of cohesional entanglements present in theinitial rubber sample. The re-appearance of a small stress peak and the increase of modu-lus on further swelling are interpreted as being of the same nature as the phenomenon ofanti-plasticization. It is the result of forming some new cohesional entanglements of largerbinding energies through longer range chain segmental motions excited after the disruptionof the previously existing cohesional entanglements in the rubber. Thus an understand-ing of the stress peak on stretching a high molar mass rubber and the phenomenon ofanti-plasticization on molecular level has been put forward." @default.
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- W1597448329 date "1997-12-20" @default.
- W1597448329 modified "2023-09-24" @default.
- W1597448329 title "ON THE ORIGIN OF STRESS PEAK IN UNI-AXIAL STRETCHING OF AMORPHOUS POLYMERS" @default.
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