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- W1597806559 abstract "Reaction of RNSNR (R = t-C 4 H 9 , 4-MeC 6 H 4 ) with (Fe 2 (CO) 9 [leads to the rupture of one or two NS double bonds as evidenced by the formation of a number of complexes containing RNS, RN and S fragments. In the case of R = t-C 4 H 9 and 4-MeC 6 H 4 the RNS fragment behaves as a four-electron donor ligand, with the NS bond still double, and as a six-electron donor ligand with the NS bond single, bridging two iron atoms in [Fe 2 (CO) 7 (RNS)] and [Fe 2 (CO) 6 (RNS)], respectively. Insertion of CO into the NS bond of [Fe 2 (CO) 6 (RNS)] yields [Fe 2 (CO) 6 {RNC(O)S}]; a crystal structure determination has been carried out for the product with R = 4-MeC 6 H 4 . Heating of the solid complex affords azotoluene, which is also isolated from the reaction mixtures. In the case of R = t-C 4 H 9 [Fe 2 (CO) 6 S 2 ], [Fe 3 (CO) 9 S 2 ] and [Fe 3 (CO) 9 (RNS)S] are also formed. A crystal structure determination of the last compound reveals a prismane type structure, in which both a six-electron donor RNS fragment and a four-electron donor S atom are linked to the three iron atoms. For R = 4-MeC 4 H 4 a different trinuclear iron complex [Fe 3 (CO) 9 (RN)S] was isolated, and the structure was established by a crystal structure determination; a nitrene fragment (RN) as well as a S atom are both triply bridging to a non linear array of three iron atoms of the Fe 3 (CO) 9 skeleton." @default.
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- W1597806559 date "1979-05-01" @default.
- W1597806559 modified "2023-09-26" @default.
- W1597806559 title "Cumulated double bond systems as ligands" @default.
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- W1597806559 doi "https://doi.org/10.1016/s0022-328x(00)92071-0" @default.
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