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- W1597841294 abstract "C5Me5Rh(CO)2 (I) reacts with PMe3 and P2Me4 to give C5Me5Rh(CO)PMe3 (II) and C5Me5Rh(CO)P2Me4 (VIII), respectively, in high yields. Reactions of II with acids HX yields stable salts IIIa–IIIc of the hydridorhodium cation [C5Me5RhH(CO)PMe3]+, whereas methyl and ethyl iodide give the acyl complexes C5Me5RhI(COR)PMe3 (IV,V); the latter react with AgPF6 to form [C5Me5RhR(CO)PMe3]PF6 (VI, VII). Treatment of the tetramethyldiphosphine complex VIII with MeI in 1 : 1 molar ratio yields C5Me5RhI(COMe)P2Me4 (X), which with excess MeI forms [C5Me5RhI(COMe)P2Me5]I (XI). The syntheses of [C5Me5RhMe(CO)P2Me4]X (XIIa: X = BF4; XIIb: X = PF6), [C5Me5RhMe(CO)P2Me5](PF6)2 (XIII) and the dinuclear rhodium(I) complex [C5Me5Rh(CO)]-(μ-P2Me4) (IX) are also described." @default.
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- W1597841294 date "1981-10-01" @default.
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- W1597841294 title "Basic Metals" @default.
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- W1597841294 doi "https://doi.org/10.1016/s0022-328x(00)81012-8" @default.
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