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- W1598710184 abstract "Abstract Individual surfactant adsorption was measured for well-defined mixtures of isomerically pure alkylbenzene sulfonates and polydisperse alkylphenol polyethoxylates adsorbing on kaolinite and alumina from aqueous solutions. All studies were at surfactant concentrations well above the CMC. These mixtures, which form nonideal mixed micelles, were also found to form nonideal mixed hemimicelles; i.e., adsorption is higher than that predicted for a mixture where inter-component lateral interactions are of magnitude similar to those between like components. Therefore, total adsorption of these mixtures can be higher than that of the individual surfactants of which they are composed. However, if one of the surfactant components adsorbed negligibly, mixed hemimicelles were not formed and both component and total mixture adsorption could be very low. This can be achieved by using nonionic surfactants with a large number of ethylene oxide units. The length of the anionic alkyl chain has little effect, and that of the nonionic surfactant has a small effect on the nonideality of the mixed hemimicelles. Results on the two substrates are qualitatively consistent with each other." @default.
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- W1598710184 date "1982-02-01" @default.
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- W1598710184 title "Adsorption of surfactants on mineral oxide surfaces from aqueous solutions" @default.
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- W1598710184 doi "https://doi.org/10.1016/0021-9797(82)90015-7" @default.
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