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- W1598730708 abstract "The kinetics of the heterogeneously catalyzed hydrogenation of 1,3-butadiene and mixtures of 1-butyne/1,3-butadiene have been investigated for a Pd/Al2O3 egg-shell catalyst. In contrast to the hydrogenation of butenes, the gas phase hydrogenation of 1,3-butadiene shows a restricted reproducibility. This behaviour is traced back to the very dense layer of strongly and rigidly adsorbed Butadiene molecules. The reaction order of the 1,3-butadiene hydrogenation is >1 with respect to hydrogen and <0 with respect to 1,3-butadiene. The hydrogenation of 1-butyne/1,3-butadiene mixtures gains an, increasing preference for the 1-butyne hydrogenation with increasing dilution of 1-butyne and decreasing partial pressure of hydrogen. The assumption is made that in this case 1-butyne is hydrogenated on active sites that are not accessible by 1,3-butadiene." @default.
- W1598730708 created "2016-06-24" @default.
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- W1598730708 date "2000-01-01" @default.
- W1598730708 modified "2023-10-17" @default.
- W1598730708 title "Kinetic studies on the hydrogenation of 1,3-butadiene, 1-butyne and their mixtures" @default.
- W1598730708 cites W2032843567 @default.
- W1598730708 doi "https://doi.org/10.1016/s0167-2991(00)80770-3" @default.
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