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- W1600462886 abstract "The donor numbers (DN) of a series of 20 phosphoramides with general structure (R 2 N)(X 2 N)(Y 2 N)P=O (with R,X and Y alkyl radicals, nitrogen-heterocycles or hydrogen atoms) were revised on the basis of a series of rather simple considerations. It is shown that all the phosphoramides considered even after the revision are characterized by high DN. In a scale of 163 different type of solvent molecules, the phosphoramides are all collocated with their DN above 35 Kcal/mol till 50 Kcal/mol. The extremely high DN value reported previously for TEPA, is now revised to 50 Kcal/mol. The highest DN values in the phosphoramides considered were found in (aziridino) 3 P=O (TEPA), (NHEt) 3 P=O and in (Pyrrolidino) 3 P=O." @default.
- W1600462886 created "2016-06-24" @default.
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- W1600462886 date "2015-03-02" @default.
- W1600462886 modified "2023-09-23" @default.
- W1600462886 title "A REVISION OF THE GUTMANN DONOR NUMBERS OF A SERIES OF PHOSPHORAMIDES INCLUDING TEPA" @default.
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- W1600462886 doi "https://doi.org/10.17628/ecb.2015.4.92-97" @default.
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