Matches in SemOpenAlex for { <https://semopenalex.org/work/W1601074188> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W1601074188 endingPage "1896" @default.
- W1601074188 startingPage "1889" @default.
- W1601074188 abstract "Hydrolyses of p-nitrophenyl acetate (PNPA) and 3-acetoxy-N,N,N-trimethylanilinium iodide (ANTI) catalyzed by poly[p-vinyl(thiophenol)-co-acrylic acid] (PSH) were studied in the pH range of 8 – 9,5. The reaction of PNPA followed pseudo-first-order kinetics and was found to be catalyzed by the thiophenolate ions on the polymer backbone. In the case of positively charged ANTI, the rate of catalysis showed substrate saturation phenomena and could be described by a Michaelis-Menten kinetics. This indicates that this reaction proceeds via a complex formed by electrostatic interaction between the substrate and the negatively charged polymer catalyst. When ionic strength was increased to 0,12 mol/l the reaction did not further follow the Michaelis-Menten kinetics, suggesting that the complexation constant or the reaction rate of the complex might vary with the amount of the substrate incorporated in the polymer domain. Positively charged N,N,N-trimethylanilinium iodide competively inhibited the PSH-catalyzed hydrolysis of ANTI." @default.
- W1601074188 created "2016-06-24" @default.
- W1601074188 creator A5009134968 @default.
- W1601074188 creator A5042821771 @default.
- W1601074188 creator A5046917671 @default.
- W1601074188 creator A5062264504 @default.
- W1601074188 date "1980-09-01" @default.
- W1601074188 modified "2023-09-26" @default.
- W1601074188 doi "https://doi.org/10.1002/macp.1980.021810910" @default.
- W1601074188 hasPublicationYear "1980" @default.
- W1601074188 type Work @default.
- W1601074188 sameAs 1601074188 @default.
- W1601074188 citedByCount "4" @default.
- W1601074188 countsByYear W16010741882022 @default.
- W1601074188 crossrefType "journal-article" @default.
- W1601074188 hasAuthorship W1601074188A5009134968 @default.
- W1601074188 hasAuthorship W1601074188A5042821771 @default.
- W1601074188 hasAuthorship W1601074188A5046917671 @default.
- W1601074188 hasAuthorship W1601074188A5062264504 @default.
- W1601074188 hasConcept C111368507 @default.
- W1601074188 hasConcept C121332964 @default.
- W1601074188 hasConcept C127313418 @default.
- W1601074188 hasConcept C148898269 @default.
- W1601074188 hasConcept C155647269 @default.
- W1601074188 hasConcept C161790260 @default.
- W1601074188 hasConcept C175113610 @default.
- W1601074188 hasConcept C178790620 @default.
- W1601074188 hasConcept C181199279 @default.
- W1601074188 hasConcept C184651966 @default.
- W1601074188 hasConcept C185592680 @default.
- W1601074188 hasConcept C187428577 @default.
- W1601074188 hasConcept C188027245 @default.
- W1601074188 hasConcept C2777289219 @default.
- W1601074188 hasConcept C2778870691 @default.
- W1601074188 hasConcept C2779801612 @default.
- W1601074188 hasConcept C28212737 @default.
- W1601074188 hasConcept C521977710 @default.
- W1601074188 hasConcept C62520636 @default.
- W1601074188 hasConcept C64915919 @default.
- W1601074188 hasConcept C93391505 @default.
- W1601074188 hasConcept C94412978 @default.
- W1601074188 hasConceptScore W1601074188C111368507 @default.
- W1601074188 hasConceptScore W1601074188C121332964 @default.
- W1601074188 hasConceptScore W1601074188C127313418 @default.
- W1601074188 hasConceptScore W1601074188C148898269 @default.
- W1601074188 hasConceptScore W1601074188C155647269 @default.
- W1601074188 hasConceptScore W1601074188C161790260 @default.
- W1601074188 hasConceptScore W1601074188C175113610 @default.
- W1601074188 hasConceptScore W1601074188C178790620 @default.
- W1601074188 hasConceptScore W1601074188C181199279 @default.
- W1601074188 hasConceptScore W1601074188C184651966 @default.
- W1601074188 hasConceptScore W1601074188C185592680 @default.
- W1601074188 hasConceptScore W1601074188C187428577 @default.
- W1601074188 hasConceptScore W1601074188C188027245 @default.
- W1601074188 hasConceptScore W1601074188C2777289219 @default.
- W1601074188 hasConceptScore W1601074188C2778870691 @default.
- W1601074188 hasConceptScore W1601074188C2779801612 @default.
- W1601074188 hasConceptScore W1601074188C28212737 @default.
- W1601074188 hasConceptScore W1601074188C521977710 @default.
- W1601074188 hasConceptScore W1601074188C62520636 @default.
- W1601074188 hasConceptScore W1601074188C64915919 @default.
- W1601074188 hasConceptScore W1601074188C93391505 @default.
- W1601074188 hasConceptScore W1601074188C94412978 @default.
- W1601074188 hasIssue "9" @default.
- W1601074188 hasLocation W16010741881 @default.
- W1601074188 hasOpenAccess W1601074188 @default.
- W1601074188 hasPrimaryLocation W16010741881 @default.
- W1601074188 hasRelatedWork W1601074188 @default.
- W1601074188 hasRelatedWork W1980748635 @default.
- W1601074188 hasRelatedWork W1983817318 @default.
- W1601074188 hasRelatedWork W1984691574 @default.
- W1601074188 hasRelatedWork W1992276599 @default.
- W1601074188 hasRelatedWork W2081110519 @default.
- W1601074188 hasRelatedWork W2359278924 @default.
- W1601074188 hasRelatedWork W2375430892 @default.
- W1601074188 hasRelatedWork W2443188929 @default.
- W1601074188 hasRelatedWork W2624890242 @default.
- W1601074188 hasVolume "181" @default.
- W1601074188 isParatext "false" @default.
- W1601074188 isRetracted "false" @default.
- W1601074188 magId "1601074188" @default.
- W1601074188 workType "article" @default.