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- W160135296 abstract "Close-packed monolayers of hexadecanol, octadecanol, octadecanoic acid, and heptadecylamine at the gas-water interface, which are known to retard the passage of water vapor, have been shown to retard the passage of other gases as well. The permeabilities of these monolayers to carbon dioxide, to oxygen, and to nitrous oxide are of the same magnitude (about 10-3 cm/sec) and considerably lower than the permeability to water vapor. The relative permeabilities of the different monolayers, however, agree with the literature on water vapor. The activation energy for the diffusion of a gas molecule through the whole monolayer is of an order of magnitude lower than that found for water permeability, but the activation energy per CH2 group was found to be about 360 cal/mole, in satisfactory agreement with the results for water vapor. The differences in the magnitudes of the permeabilities and of the activation barriers of whole monolayers to various gases are explained tentatively on the basis of the interfering effect of water vapor. The biological implications of this work are briefly discussed." @default.
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- W160135296 date "1962-01-01" @default.
- W160135296 modified "2023-09-23" @default.
- W160135296 title "The Permeability of Monolayers to Several Gases" @default.
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- W160135296 doi "https://doi.org/10.1016/b978-1-4832-2947-8.50011-2" @default.
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