Matches in SemOpenAlex for { <https://semopenalex.org/work/W1601640383> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W1601640383 endingPage "970" @default.
- W1601640383 startingPage "959" @default.
- W1601640383 abstract "Esters of oxalic acid, 3,4-dihydroxy-3-cyclobutene-1,2-dione (squaric acid), and oxamic acid, are reduced cathodically at modest potentials. In aprotic solvent, and on the cyclic voltammetric time scale, the esters are cleaved to the corresponding alkane. For oxalates, the mechanism of cathodic cleavage was investigated thoroughly by voltammetry, coulometry, and detailed product analysis. On the time scale of controlled potential electrolysis the rapid electrogenerated base-catalysed hydrolysis of the esters by adventitious water competes with cathodic cleavage. Similarly, rapid base-catalysed transesterification involving oxalates and added alcohols is observed which provides a practical method of reductively cleaving alcohols to alkanes by co-electrolysis of a mixture of alcohol and readily available oxalate (e.g. diethyloxalate). The leaving group in such cathodic fragmentation is the half-ester anion and the efficiency of reaction depends on the stability of the other, radical, fragment." @default.
- W1601640383 created "2016-06-24" @default.
- W1601640383 creator A5017763702 @default.
- W1601640383 creator A5033265133 @default.
- W1601640383 creator A5067642620 @default.
- W1601640383 date "1987-01-01" @default.
- W1601640383 modified "2023-10-10" @default.
- W1601640383 title "Electro-organic reactions" @default.
- W1601640383 cites W1538944932 @default.
- W1601640383 cites W1565037811 @default.
- W1601640383 cites W1982439702 @default.
- W1601640383 cites W1990802104 @default.
- W1601640383 cites W2005105272 @default.
- W1601640383 cites W2013911062 @default.
- W1601640383 cites W2026774907 @default.
- W1601640383 cites W2053173378 @default.
- W1601640383 cites W2081002944 @default.
- W1601640383 cites W2165821398 @default.
- W1601640383 cites W2171342809 @default.
- W1601640383 cites W2323015697 @default.
- W1601640383 cites W2323860313 @default.
- W1601640383 cites W2325849950 @default.
- W1601640383 cites W93482431 @default.
- W1601640383 doi "https://doi.org/10.1016/s0040-4020(01)90033-x" @default.
- W1601640383 hasPublicationYear "1987" @default.
- W1601640383 type Work @default.
- W1601640383 sameAs 1601640383 @default.
- W1601640383 citedByCount "8" @default.
- W1601640383 countsByYear W16016403832013 @default.
- W1601640383 countsByYear W16016403832017 @default.
- W1601640383 countsByYear W16016403832018 @default.
- W1601640383 countsByYear W16016403832020 @default.
- W1601640383 countsByYear W16016403832022 @default.
- W1601640383 crossrefType "journal-article" @default.
- W1601640383 hasAuthorship W1601640383A5017763702 @default.
- W1601640383 hasAuthorship W1601640383A5033265133 @default.
- W1601640383 hasAuthorship W1601640383A5067642620 @default.
- W1601640383 hasConcept C109379892 @default.
- W1601640383 hasConcept C147789679 @default.
- W1601640383 hasConcept C163127949 @default.
- W1601640383 hasConcept C17525397 @default.
- W1601640383 hasConcept C178790620 @default.
- W1601640383 hasConcept C179104552 @default.
- W1601640383 hasConcept C185592680 @default.
- W1601640383 hasConcept C2776351790 @default.
- W1601640383 hasConcept C2777869211 @default.
- W1601640383 hasConcept C2778406045 @default.
- W1601640383 hasConcept C2781346138 @default.
- W1601640383 hasConcept C52859227 @default.
- W1601640383 hasConcept C68801617 @default.
- W1601640383 hasConcept C94412978 @default.
- W1601640383 hasConceptScore W1601640383C109379892 @default.
- W1601640383 hasConceptScore W1601640383C147789679 @default.
- W1601640383 hasConceptScore W1601640383C163127949 @default.
- W1601640383 hasConceptScore W1601640383C17525397 @default.
- W1601640383 hasConceptScore W1601640383C178790620 @default.
- W1601640383 hasConceptScore W1601640383C179104552 @default.
- W1601640383 hasConceptScore W1601640383C185592680 @default.
- W1601640383 hasConceptScore W1601640383C2776351790 @default.
- W1601640383 hasConceptScore W1601640383C2777869211 @default.
- W1601640383 hasConceptScore W1601640383C2778406045 @default.
- W1601640383 hasConceptScore W1601640383C2781346138 @default.
- W1601640383 hasConceptScore W1601640383C52859227 @default.
- W1601640383 hasConceptScore W1601640383C68801617 @default.
- W1601640383 hasConceptScore W1601640383C94412978 @default.
- W1601640383 hasIssue "5" @default.
- W1601640383 hasLocation W16016403831 @default.
- W1601640383 hasOpenAccess W1601640383 @default.
- W1601640383 hasPrimaryLocation W16016403831 @default.
- W1601640383 hasRelatedWork W1972183064 @default.
- W1601640383 hasRelatedWork W2000061764 @default.
- W1601640383 hasRelatedWork W2013890072 @default.
- W1601640383 hasRelatedWork W2035223230 @default.
- W1601640383 hasRelatedWork W2062486330 @default.
- W1601640383 hasRelatedWork W2065035880 @default.
- W1601640383 hasRelatedWork W2123329701 @default.
- W1601640383 hasRelatedWork W2337758717 @default.
- W1601640383 hasRelatedWork W2351812690 @default.
- W1601640383 hasRelatedWork W74375557 @default.
- W1601640383 hasVolume "43" @default.
- W1601640383 isParatext "false" @default.
- W1601640383 isRetracted "false" @default.
- W1601640383 magId "1601640383" @default.
- W1601640383 workType "article" @default.