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- W1603380979 abstract "The adsorption and reactions of methane on Fe2O3, MoO3 and ferric molybdate catalysts have been studied using the Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) technique. This study was carried out at the temperature of 703 K and, at the pressure of 30 bar. The Mo/Fe ratio was changed from 1 to 5, thus giving a broad range of atomic ratios. The formation of methoxys (OCH3), adsorbed formaldehyde, dioxymethylene (OCH2O), and formate (OCHO) species were observed on the catalyst surface. A mechanism based on the reaction of methane with the surface of the ferric molybdate catalyst to produce methoxides which are further oxidized to dioxymethylen is proposed. The formation of carbon oxides is attributed to either the decomposition of dioxymethylene or to the formation of formate species. This study revealed that MoO3 is the active catalyst for the partial oxidation of methane to formaldehyde and Fe2O3 gives carbon oxides. Both methanol and formaldehyde can be obtained from the ferric molybdate catalysts." @default.
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- W1603380979 date "1997-01-01" @default.
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- W1603380979 title "Adsorption and reactions of methane on ferric molybdate using DRIFTS technique" @default.
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- W1603380979 doi "https://doi.org/10.1016/s0167-2991(97)80409-0" @default.
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