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- W160393669 abstract "Lithium monoxide is chemically inert towards transition metals and steels but at high temperatures and low pressures, corrosion can be induced by extracting lithium. For example, Cr + 2Li2O → LiCrO2 + 3Li ↑ The rates of corrosion of the steels 316 (18% Cr) and 1.4914 (11% Cr) under 10-2 Pa have been measured by microscopy and by changes in electrical resistance. The rate of loss of metal from 316 steel is given by log (μm/h) = 14.05 - 16600/T 1167 ≤ T(K) ≤ 1320 Like 316, the 1.4914 steel is chemically resistant to pure Li2O in an isothermal sealed system at least up to 1198K, but at 1273K and under dynamic vacuum, both steels corrode at about the same rate. Corrosion is primarily by penetration of the steel by Li2O accompanied by diffusion of Cr in the opposite direction. The substrate steel becomes converted to a Cr-depleted layer beneath an outer layer of LiCrO2. Some Li5FeO4 may have diffused or evaporated from the surface. For 1.4914 steel in Li2SiO3, the corrosion rate under 10-2 Pa is given by log (μm/h) = 0.03 - 1600/T 673 ≤ T(K) ≤ 1223 At 1273K, the corrosion of 1.4914 by Li2SiO3 would be about 100 times slower than by Li2O. With 1.4914 and Li2SiO3, a corrosion scale, which contains LiCrO2, forms exterior to the steel which consequently is depleted of Cr." @default.
- W160393669 created "2016-06-24" @default.
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- W160393669 date "1986-01-01" @default.
- W160393669 modified "2023-09-26" @default.
- W160393669 title "THE CORROSION OF STEELS BY LITHIUM MONOXIDE AND BY LITHIUM SILICATE" @default.
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- W160393669 doi "https://doi.org/10.1016/b978-1-4832-8376-0.50126-1" @default.
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