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• W160458114 abstract "Steroidal Δ4-3,6-diketones undergo two diagnostically significant fission reactions after electron impact. The first is due to scission of the 9–10 and 6–7 bonds with and without hydrogen transfer to yield peaks at m/e 137 and 136, which correspond to ring A and carbon atom 6. The other involves cleavage of the 9–10 and 7–8 linkages with rearrangement of one hydrogen atom and charge retention with rings C and D. Consideration of the mass spectral fragmentation can thus yield valuable information on the substitution pattern of Δ4-3,6-diketones." @default.
• W160458114 created "2016-06-24" @default.
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• W160458114 date "1965-07-01" @default.
• W160458114 modified "2023-10-02" @default.
• W160458114 title "Mass spectrometry in structural and stereochemical problems LXXVIII.11Paper LXXVII, Fritz, H., Budzikiewicz, H. and Djerassi, C., Ber., in press. steroidal Δ4-3,6-diketones" @default.
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• W160458114 doi "https://doi.org/10.1016/0039-128x(65)90029-2" @default.
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