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- W1604720004 abstract "Abstract A highly stereoselective protocol is reported for customizing functionalized carbocyclic building blocks (β‐hydroxy esters) and bicyclic lactones with a stereoarray that contains contiguous tertiary carbinol and all‐carbon stereocenters. The efficient asymmetric induction and diastereofacial selective addition of allyl and propargyl indiums to hindered α,α‐disubstituted cycloalkanones is presented. The stereochemistry of representative products was unequivocally established from single‐crystal X‐ray crystal structure analyses, and a plausible reaction pathway was proposed to support the high diastereofacial selectivity." @default.
- W1604720004 created "2016-06-24" @default.
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- W1604720004 date "2013-03-01" @default.
- W1604720004 modified "2023-10-03" @default.
- W1604720004 title "Construction of Functionalized Carbocycles Having Contiguous Tertiary Carbinol and All‐Carbon Stereogenic Centers" @default.
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- W1604720004 doi "https://doi.org/10.1002/ejoc.201201382" @default.
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