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- W1605249000 abstract "Publisher Summary This chapter describes the effects of various surfactant and stabilizer systems as they apply to polymerizations in CO 2 . For CO 2 to be an effective continuous phase for polymerizations, heterogeneous reaction systems must necessarily be developed analogous to classical emulsion, inverse emulsion, dispersion, suspension, and precipitation polymerization processes. With some highly reactive monomers, such as acrylic acid and tetrafluoroethylene, free-radical precipitation polymerization can afford polymers with high yields and molecular weight. However, many industrial monomers require the utilization of surfactant stabilized reaction conditions. This chapter discusses the utilization of nonionic—homopolymer, block copolymer, and reactive macromonomer—surfactants consisting of covalently bound CO 2 -philic and CO 2 -phobic segments in the dispersion polymerization of various CO 2 -insoluble polymers. These reactions produce a stabilized polymer colloid in CO 2 solution and dry, free flowing powders after isolation." @default.
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- W1605249000 date "1996-01-01" @default.
- W1605249000 modified "2023-09-25" @default.
- W1605249000 title "The importance of surfactants for polymerizations in carbon dioxide" @default.
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- W1605249000 doi "https://doi.org/10.1016/s0921-8610(96)80006-9" @default.
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