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- W1605648728 abstract "Abstract Single crystals of Ba6Cu11F34 were isolated from a melt corresponding to the composition 25 BaF275 CuF2. They are triclinic: P 1 , a = 7.490(1) A, b = 10.031(2) A, c = 10.271(3) A, α = 82.98(2)°, β = 73.88(2)°, γ = 70.42(2)°, Z = 1. The structure was determined from 3604 independent reflections using the program SHELX (R = 0.054, Rw = 0.052). The three-dimensional network is built from units of three edge-sharing octahedra connected by complex groups of octahedra. All the copper octahedra are elongated and the barium ions exhibit 11- or 12-fold coordination. The structural relations to Ba6Zn7F26 and Ba2Ni3F10 are discussed." @default.
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- W1605648728 date "1986-04-01" @default.
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- W1605648728 title "Complex copper(II) fluorides" @default.
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- W1605648728 doi "https://doi.org/10.1016/0022-4596(86)90227-6" @default.
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