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• W1605945339 endingPage "6404" @default.
• W1605945339 startingPage "6393" @default.
• W1605945339 abstract "Room temperature Mn K-edge extended x-ray absorption fine structure (EXAFS) studies were carried out on La$_{1-x}$Sr$_x$MnO$_{3+delta}$ (x = 0.1 to 0.9) compounds. It is found from the detailed EXAFS analysis that the local structure around Mn sites is different from the global structure inferred from x-ray diffraction, especially for x <= 0.4, indicating presence of local distortions in MnO$_6$ octahedra. For the rhombohedral compounds, x = 0.1 to 0.3 the distortion is maximum for x = 0.1 and two bond lengths are seen- short one in basal plane and long one in apical plane. For compounds with x = 0.4 to 0.8 two short bonds in basal plane and four long bonds- two in the basal plane and remaining two in the apical plane are seen. For the compounds up to x = 0.3 compositions long bond length decreases and short bond length increases with increase in x whereas for the compounds 0.4 <= x <= 0.8 both types of bond lengths decrease. Such behaviour of bond lengths is an indication of the changed nature of distortion from Jahn-Teller type to breathing type at x = 0.4 composition." @default.
• W1605945339 created "2016-06-24" @default.
• W1605945339 creator A5018304206 @default.
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• W1605945339 date "2005-09-30" @default.
• W1605945339 modified "2023-09-24" @default.
• W1605945339 title "Local distortion of MnO₆octahedron in La_1−<i>x</i>Sr_<i>x</i>MnO_3+δ(<i>x</i>= 0.1–0<i>.</i>9): an EXAFS study" @default.
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• W1605945339 doi "https://doi.org/10.1088/0953-8984/17/41/010" @default.
• W1605945339 hasPublicationYear "2005" @default.
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