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- W1606282164 abstract "The syntheses of three types of sugar nitrones (aldonitrone, ketonitrone and α-β unsaturated aldonitrone) are described. On 1,3-dipolar cycloaddition with phenylacetylene, the aldonitrone gave two Δ4-isoxazolines epimeric at the new asymetric carbon, while the same reaction on the ketonitrone led to a spiro-Δ4-isoxazoline. The reaction of these nitrones with carbon nucleophiles like phenylethynylmagnesium bromide constitutes a novel chain-extension reaction in carbohydrate chemistry." @default.
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- W1606282164 date "1972-04-20" @default.
- W1606282164 modified "2023-09-23" @default.
- W1606282164 title "Dérivés C-glycosyliques. VII. Synthèse et réactions de nitrones dérivées de sucres. Communication préliminaire" @default.
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- W1606282164 doi "https://doi.org/10.1002/hlca.19720550422" @default.
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