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- W1606978321 abstract "Na 2 Mn 2(1 − x ) Cd 2 x Fe(PO 4 ) 3 (0 ≤ x ≤ 1) phosphates were prepared by solid state reaction and characterized by powder X-ray diffraction, magnetic susceptibility and Mossbauer spectroscopy. The X-ray diffraction patterns indicated the formation of a continuous solid solution which crystallizes in the alluaudite structural type characterized by the general formula X (2) X (1) M (1) M (2) 2 (PO 4 ) 3 . The cation distribution, deduced from a structure refinement of the x = 0, 0.5 and 1 compositions, is ordered in the X (2) sites and disordered in the remaining X (1), M (1) and M (2) sites. The magnetic susceptibility study revealed an antiferromagnetic behaviour of the studied compounds. The 57 Fe Mossbauer spectroscopy confirmed the structural results and proved the exclusive presence of Fe 3+ ions." @default.
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- W1606978321 date "2011-10-01" @default.
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- W1606978321 title "Structural study by X-ray diffraction, magnetic susceptibility and Mössbauer spectroscopy of the Na2Mn2(1−x)Cd2xFe(PO4)3 (0≤x≤1) solid solution" @default.
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- W1606978321 doi "https://doi.org/10.1016/j.crci.2011.04.002" @default.
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