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- W1606993721 abstract "The results of a critical reexamination of previous experimental observations of the (X 2Πg) nsσg 1,3Πg Rydberg states of O2 are employed to optimize a coupled-channel Schrödinger-equation (CSE) model describing rovibronic interactions among a number of Πg1,3 Rydberg and valence states. The results of calculations using this CSE model are compared with the experimental energy-level and predissociation linewidth data base. As a result of the optimization process, relevant potential-energy curves and Rydberg–valence, Rydberg–Rydberg, and valence–valence interactions are characterized for Πg1,3 states in the ∼6.5–9.5 eV region above the ground state of O2. The precision of these characterizations and the interpretation of the experimental observations are found to be limited by the quality of the existing data, which exhibit a number of inconsistencies that cannot be reconciled without new, well-characterized experimental studies. In spite of these difficulties, the present CSE model, as currently parametrized, represents a significant improvement over previous work, enabling identification of a number of previously unassigned spectral features associated with perturbation of the 3sσg d 1Πg state by the II 1Πg valence state and an anomalous J sensitivity in predissociation branching ratios for the d(v=1) level. In addition, the electronic structure and predissociation of the nsσg states for n⩾4 are found to be strongly influenced by nsσg−(n−1)dσg Rydberg–Rydberg interactions." @default.
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- W1606993721 date "1999-07-01" @default.
- W1606993721 modified "2023-10-11" @default.
- W1606993721 title "The (X 2Πg) nsσg 1,3Πg Rydberg states of O2: Spectra, structures, and interactions" @default.
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- W1606993721 cites W1965180785 @default.
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- W1606993721 doi "https://doi.org/10.1063/1.479264" @default.
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