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- W1607457569 abstract "The group 13 elements are chemically rather diverse: boron is a moderately electropositive nonmetal, whereas aluminum, gallium, indium, and thallium are all metals. The covalent chemistry that is discussed encounter in this chapter, therefore, is somewhat limited. The chapter discusses group 13 compounds Lewis acids, hydroboration, group 13-based reducing agents, 13-15 compounds (from borazine to gallium arsenide), low-oxidation state compounds, boryl anions, indium-mediated allylations, and thallium reagents. The trivalent state is the normal state for all the elements, except thallium. When the coordination number is also 3, the compounds act as powerful Lewis acids. The monovalent state is well established for all the elements except boron, but is unstable and reactive for aluminum and gallium. Low-valent and low oxidation-state aluminum and gallium chemistry has been an active area of research in recent years." @default.
- W1607457569 created "2016-06-24" @default.
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- W1607457569 date "2014-08-01" @default.
- W1607457569 modified "2023-09-27" @default.
- W1607457569 title "Group 13 Elements" @default.
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- W1607457569 doi "https://doi.org/10.1002/9781118924525.ch3" @default.
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