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- W1607741311 abstract "In the photochemical decomposition of triazene RNNNR1R2 in CH3CN solutions, where R was (3-HOOC, di-HOOC, 4-HOOC, 4-CN)phenyl and R1, R2 were CH3, CH2H5, CH(CH3)2, CH2CH2OH, the corresponding phenyl-substituted radicals were identified as 5,5-dimethyl-1-pyrroline N-oxide (DMPO) or (CH3)3CNO adducts. The reaction is described by a first-order kinetics with a half lifetime of 7 s. If R was di-3,5-CON3-C6H3, a nitrogen-centred radical was found on radiation in the solid state as well as in CH3CN solution with DMPO as spin trap." @default.
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- W1607741311 date "1993-12-01" @default.
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- W1607741311 doi "https://doi.org/10.1002/macp.1993.021941217" @default.
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