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- W1608273410 abstract "Abstract The configurations of C 12 , C 13 (and C 17 ) in an acetolysis product (IVa) of diacetyltetrahydrojervine (IIIa) and its derivatives (Va to VIIIa) have been established. It follows that dihydro- and tetrahydrojervine are correctly represented by formulas II and III, (C/D trans , 12βH) rather than XXXV and XXIX (C/D cis , 12αH), respectively. The stereochemistry of the hydrogenation results of jervine (I) and the related compounds is rationalized on the basis of these formulas and the spectral data. The ORD curves of 12-epimeric 11-oxoetiojervanes and 11-oxoiminojervanes with established configurations are also presented and the summarized result reveals that the amplitudes fall within the limits of −150 ∼ −190° for the C/D trans -fused compounds and of −70 ∼ −100° for the cis -fused." @default.
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- W1608273410 date "1969-01-01" @default.
- W1608273410 modified "2023-10-09" @default.
- W1608273410 title "The stereochemistry of dihydrojervine and related compounds" @default.
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- W1608273410 doi "https://doi.org/10.1016/s0040-4020(01)83026-x" @default.
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