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- W1608508952 abstract "Le n-butyl lithium réagit de façon stéréospécifique sur les iodométhyl-2 tosyloxy-1 cyclohexanes et ènes-4 conduisant aux bicyclo(4.1.0)heptane (ène) cis à partir des isomères trans et méthylène cyclohexane (ène) à partir des isomères cis. Un parallèle a été établi entre la réaction étudiée et la dshydrohalogénation alcaline des halohydrines-1,2 cyclaniques; un mécanisme de formation pour chacun des produits a été proposé. The reaction of cis and rans 2-iodomethyl 1-tosyloxycyclohexanes and 4-enes with nBuLi was studied and found to be stereospecific, the products being respectively bicyclo(4.1.0)hexane (ene) cis and methylene cyclohexane (ène). A parallel is drawn between this reaction and alkaline deshydrohalogenation of cyclic 1,2-halohydrins; a reaction pathway is proposed." @default.
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- W1608508952 date "1976-01-01" @default.
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- W1608508952 title "Reaction d'elimination-1,3" @default.
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- W1608508952 doi "https://doi.org/10.1016/0040-4020(76)80144-5" @default.
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