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- W1608764462 abstract "Three novel complexes containing ligand of N-phenyl norcantharidin acylamide acid (HL = 3-phenyl carbamoyl-7-oxabicyclo [2.2.1] heptane-2-carboxylic acid, C14H15NO4) were synthesized and characterized by elemental analyses, conductivity measurement, IR spectra, and thermogravimetric analysis. The general formulas of the complexes were [RE(L)(NO3)(H2O)2]NO3·2H2O, (RE ˭ Y(III), Gd(III), Dy(III)). The results indicated that the oxygen atoms of carbonyl, cyclic ether, and carboxylate coordinated to RE (III), and there was also one nitrate taking part in coordination. RE(III) and HL formed 1:1 chelate complexes and the suggested coordination number was eight. The interactions between the complexes and DNA have been investigated by means of fluorescence spectra, viscosity, and agarose gel electrophoresis. The results showed that the complexes could bind to DNA by the modes of partly intercalation. The binding abilities of the complexes with DNA follow the trend: Dy(III) complex > Gd(III) complex > Y(III) complex. The results of the agarose gel electrophoresis showed that all the complexes are capable of cleaving pBR322 plasmid DNA at physiological pH and temperature." @default.
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- W1608764462 date "2012-05-01" @default.
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- W1608764462 title "Synthesis, Characterization, DNA-Binding Studies of Rare Earth Complexes With N-Phenyl Norcantharidin Acylamide Acid" @default.
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- W1608764462 doi "https://doi.org/10.1080/15533174.2011.615041" @default.
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